Spin in a closed-shell organic molecule on a metal substrate generated by a sigmatropic reaction

Bocquet ML, Lorente N, Berndt R, and Gruber M.
https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201812121
Angewandte Chemie

Figure 1.- Sequence of transformation as obtained from density functional theory calculations. The left column shows the simulated STM images, and the right column the stick-and-ball model of the suggested electron-induced reactants.

The retinoic acid is a stable organic molecule that has been studied in the group of Prof. Berndt in Kiel using a scanning tunneling microscope (STM). By using tunneling electrons, the molecule undergoes some transformation and become spin polarized. This is most startling because the molecule is very stable in its closed-shell form (no spin) and the molecule is in contact with a gold surface that is a reservoir of electrons capable of quenching any localized spin on its surface. Bocquet and Lorente came up with a sigmatropic reaction where one of the H atoms of the molecule displaces itself thanks to the energy taken from the tunneling electron. By doing so, the molecule becomes distorted, decoupling itself from the metallic surface and creating a dangling bond where a spin is localized. Studying these radical molecules on metallic surface is an interesting field, because of both its intrinsic difficulty and the practical applications creating reactive radicals in an otherwise very passivating environment.

Authors addresses:

Dr. Bocquet: PASTEUR, Département de chimie, École normale supérieure, PSL University, Sorbonne Université, CNRS, 75005 Paris, France.

Dr. Lorente: Centro de Fısica de Materiales CFM/MPC (CSIC-UPV/EHU), Paseo Manuel de Lardizabal 5 and Donostia International Physics Center (DIPC), Paseo Manuel de Lardizabal 4, 20018 Donostia-San Sebastian, Spain.

Prof. Dr. Berndt and Dr Gruber: Institut für Experimentelle und Angewandte Physik, Christian-Albrechts-Universität, 24098 Kiel, Germany.