Quantum Nanospectroscopy Materials Physics Center Donostia-San Sebastián

Controlling quantum light with colloidal nanocrystals and hybrid cavities

We study how plasmonic nanocavities and tunable optical microcavities can control the emission of individual colloidal quantum emitters. Our goal is to improve single-photon purity, brightness, emission rate and indistinguishability without redesigning the emitter material.

Fluorescent colloidal nanocrystal samples beside a microscopy image of nanocrystals
Fluorescent colloidal nanocrystal samples and microscopy of nanocrystals.

Photonic control at the single-emitter level

The group investigates how the photonic environment around an individual emitter can control its quantum optical response. This approach aims to tune emission without changing the material structure of the emitter.

Colloidal quantum emitters

We study semiconductor quantum dots and perovskite nanocrystals as solid-state light sources with single-photon statistics.

Plasmonic light-matter coupling

We couple the radiative transitions of individual emitters to plasmonic nanocavities to control emission at the nanoscale.

Tunable optical microcavities

We use optical microcavities as tunable photonic environments for controlling brightness, emission rate and photon indistinguishability.

Current research activity

From stable perovskite nanocrystals to cavity-coupled single-photon emitters

The group’s current work programme connects materials preparation, predictive modelling and quantum-optical measurements.

  1. Synthesis and functionalisation

    Develop perovskite nanocrystals across different compositions and emission wavelengths, and study how surface ligands and polymer matrices influence optical stability.

  2. Hybrid emitter design

    Combine electromagnetic and quantum modelling with the fabrication of plasmonic nanocavities and the integration of selected nanocrystal structures.

  3. Quantum optical characterisation

    Measure individual emitters under ambient and cryogenic conditions using time-resolved spectroscopy, photon correlations and Hong-Ou-Mandel interferometry.

From nanocrystal synthesis to photon-correlation measurements

The available facilities support nanocrystal preparation, ensemble optical spectroscopy and measurements on individual quantum emitters.

Materials preparation

Nanocrystal synthesis laboratory

Facilities for the synthesis of colloidal quantum dots.

Technical details

A chemical laboratory equipped for quantum dot synthesis.

Absorption spectroscopy

Cary UV-Vis

Agilent

Technical details

UV-Vis spectrophotometer for ensemble optical measurements.

Optical spectroscopy

Cary Eclipse

Agilent

Technical details

Spectrophotometer for ensemble optical measurements.

Time-resolved microscopy

MicroTime 200

PicoQuant

Technical details

Single-particle time-resolved fluorescence and photon-correlation measurements in a Hanbury Brown and Twiss configuration with two avalanche photodetectors.

Single-particle spectroscopy

Kymera 193i

Andor

Technical details

Ultrasensitive spectrograph connected to the fluorescence microscope for spectral measurements at the single-particle level.

Femtosecond excitation

Chameleon Ultra

Coherent

Technical details

Ti:sapphire laser with pulses down to 50 fs across 680 to 1080 nm. Second-harmonic generation extends the available wavelength range to 340 to 540 nm.

Photon indistinguishability

Hong-Ou-Mandel setup

Custom-built

Technical details

Two high-speed single-photon photodetectors enable photon indistinguishability measurements.

Our team

Quantum Nanospectroscopy is part of the Nanomaterials and Spectroscopy Group. The parent group is led by Prof. Dr. Yury P. Rakovich, and its researchers work across colloidal nanomaterials, nanophotonics, spectroscopy and light-matter coupling.

Portrait of Dr. Victor Krivenkov

Dr. Victor Krivenkov

Quantum Nanospectroscopy lead

Materials Physics Center

Victor Krivenkov has more than 10 years of experience developing colloidal fluorescent nanocrystals and plasmonic nanostructures. His research focuses on light-matter-coupled quantum emitters that integrate semiconductor nanocrystals with nano- and microcavities.

Portrait of Prof. Dr. Yury P. Rakovich

Prof. Dr. Yury P. Rakovich

Head, Nanomaterials and Spectroscopy Group

Ikerbasque Research Professor Materials Physics Center

Yury P. Rakovich heads the Nanomaterials and Spectroscopy Group at the Materials Physics Center. His research covers nanophotonics, the optics of organic and inorganic hybrid nanostructures and strong light-matter interaction. He is a senior member of the Optical Society of America.

Portrait of Dr. Alexey Nikitin

Dr. Alexey Nikitin

Ikerbasque Research Professor

Donostia International Physics Center

Alexey Nikitin develops theory for optical phenomena in natural van der Waals materials, artificial low-dimensional materials and metamaterials. His research includes hyperbolic light and near-field microscopy. His previous research experience includes the University of Zaragoza and CIC nanoGUNE.

Portrait of Dr. Adam Olejniczak

Dr. Adam Olejniczak

Alumnus

Materials Physics Center

During his time with the group, Adam Olejniczak studied light-matter interactions in colloidal quantum emitters, strongly coupled plexcitonic systems and J-aggregates in photonic microcavities. He used time-correlated single-photon counting to investigate optical processes at the single-particle level. He was awarded a Juan de la Cierva fellowship.

Portrait of Mr. Jehyeok Ryu

Mr. Jehyeok Ryu

PhD student

Donostia International Physics Center

Jehyeok Ryu is a DIPC PhD student working within the Nanomaterials and Spectroscopy research line. His recent work with the group addresses the synthesis, photostability and single-photon emission of perovskite quantum dots.

Selected publications

Recent work from the group. Titles link to the publisher, DOI record or arXiv preprint.

2026

  1. PreprintarXiv:2602.11385

    When Blinking Helps: Suppressed Biexciton Emission in Lead Halide Perovskite Quantum Dots

    Olejniczak, A., Ryu, J., Di Stasio, F., Rakovich, Y., Krivenkov, V.

    arXiv preprint, arXiv:2602.11385

  2. PreprintarXiv:2601.15898

    Size-dependent Dielectric Permittivity of Perovskite Nanocrystals

    Ryu, J., Krivenkov, V., Goryashko, V., Nikitin, A., Rakovich, Y.

    arXiv preprint, arXiv:2601.15898

2025

  1. ArticleAdvanced Functional Materials

    Facile Van der Waals hBN Encapsulation and Stabilization of Perovskite Quantum Dots Emission

    Kim, J., Yamamura, K., Horder, J., Ryu, J., Zhigulin, I., Coste, N., Nikitin, A. Y., Rakovich, Y., Aharonovich, I.

    Advanced Functional Materials. DOI: 10.1002/adfm.202527591

  2. ArticleNano Letters

    Nickel Doping Unlocks Ambient-Condition Photostability in Individual Cesium Lead Bromide Perovskite Quantum Dots

    Ryu, J., Krivenkov, V., Olejniczak, A., Arruabarrena, M., Janovec, J., Hadjadj, S., Ilyn, M., Leonardo, A., Martinez-Martinez, V., Ayuela, A., Nikitin, A., Rakovich, Y.

    Nano Letters, 25(47), 16630-16636. DOI: 10.1021/acs.nanolett.5c04099

  3. ArticleApplied Physics Reviews

    Perovskite Nanocrystals as Emerging Single-Photon Emitters: Progress, Challenges, and Opportunities

    Ryu, J., Krivenkov, V., Olejniczak, A., Nikitin, A., Rakovich, Y.

    Applied Physics Reviews, 12(4), 041323. DOI: 10.1063/5.0282667

2024

  1. ArticleAPL Photonics

    On-demand Reversible Switching of the Emission Mode of Individual Semiconductor Quantum Emitters Using Plasmonic Metasurfaces

    Olejniczak, A., Lawera, Z., Zapata-Herrera, M., Chuvilin, A., Samokhvalov, P., Nabiev, I., Grzelczak, M., Rakovich, Y., Krivenkov, V.

    APL Photonics, 9(1), 016107. DOI: 10.1063/5.0170535

  2. ArticleMaterials for Quantum Technology

    Advancements and Challenges in Plasmon-Exciton Quantum Emitters Based on Colloidal Quantum Dots and Perovskite Nanocrystals

    Olejniczak, A., Rakovich, Y., Krivenkov, V.

    Materials for Quantum Technology, 4(3), 032001. DOI: 10.1088/2633-4356/ad6b6d

Contact the group

For research questions, potential collaborations or information about the group, contact Victor Krivenkov or Yury Rakovich.

Telephone

+34 943 01 89 38

Address

Materials Physics Center
Paseo de Manuel Lardizabal, 5
20018 Donostia-San Sebastián, Gipuzkoa, Spain